Chace Crawford heats up Glaceau VitaminWater’s MLB All-Star week celebration at Hudson Terrace on Monday in New York City.

The very next morning (today), the 22-year-old actor and costar Madchen Amick filmed new scenes for their hit CW series, Gossip Girl. On the show, Amick, 37, will appear as cougar Catherine Mason and tempt Nate Archibald (Crawford, 22).

Chace is also set to host opening day of Mercedes-Benz Bridgehampton Polo on Saturday.

Check out the Gossip Girl teasers below!

20+ pictures inside of VitaminWater Womanizer Chace Crawford… More Here! »

Chace Crawford films scenes with newbie Madchen Amick for their cult series, Gossip Girl, in New York City on Thursday.

Amick, 37, will appear in the first few eps of the new season as cougar Catherine Mason and tempt Nate Archibald (Crawford, 22) with a May-December romance. In the first four or five episodes, it will also be revealed that Amick’s character will also have “a surprising connection to another new character on the show.”

WHAT DO YOU THINK of Chace and Madchen’s characters as a couple?